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RESEARCH PRODUCT

Pressure and Thermally Induced Spin Crossover in a 2D Iron(II) Coordination Polymer {Fe[bipy(ttr)2]}n

Hennagii FylymonovQuanjun LiRuixin LiMaksym SeredyukLudmila BerezhnayaMengyun YuanGeorgiy LevchenkoN.a. LiedienovJosé Antonio Real

subject

Magnetic measurementsMaterials scienceCoordination polymerAnalytical chemistry02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical scienceschemistry.chemical_compoundHysteresisUltraviolet visible spectroscopychemistrySpin crossover0210 nano-technology

description

Using magnetic measurements and UV -visible spectroscopy we have studied the pressure influence on the spin crossover (SCO) properties of the 2D Fe (II) coordination polymer formulated {Fe[bipy(ttr) 2 ]} n . At variable temperature and fixed pressure, we have measured the magnetic property of this compound. Under different pressures and at room temperature, the visible spectroscopy has been observed. The magnetic experiment displays a two-step spin crossover behavior under pressure. The visible spectroscopic measurements at room temperature show a spin crossover with an asymmetric hysteresis at 0.4GPa.

yearjournalcountryeditionlanguage
2021-04-082021 5th IEEE Electron Devices Technology & Manufacturing Conference (EDTM)
https://doi.org/10.1109/edtm50988.2021.9420970