Intramolecular cyclization of chloral allyl hemiacetal under the action of the Fe(CO)5-DMF system

6533b7d7fe1ef96bd12682ec

RESEARCH PRODUCT

Intramolecular cyclization of chloral allyl hemiacetal under the action of the Fe(CO)5-DMF system

Andrey V. Ivanov A. B. Terent'ev K. I. Kobrakov N. A. Kuz'mina Katri Laihia Erkki Kolehmainen T. T. Vasil'eva V. K. Korolev

subject

chemistry.chemical_compound Chemistry Intramolecular cyclization Hemiacetal Chloral General Chemistry Medicinal chemistry Derivative (chemistry)

description

Chloral allyl hemiacetal undergoes cyclization in the presence of the Fe(CO)5-DMF system to form 3,3,5-trichloro-2-hydroxytetrahydropyran rather than a butyrolactone derivative.

year	journal	country	edition	language
1999-04-01	Russian Chemical Bulletin

https://doi.org/10.1007/bf02496261

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