0000000000146876

AUTHOR

N. A. Kuz'mina

showing 3 related works from this author

Difference in the behavior of methyl (S)-?-bromopropionate in its addition to trimethylvinylsilane depending on the method of initiation

1996

The addition of methyl (S)-2-bromopropionate to trimethylvinylsilane initiated by systems based on iron pentacarbonyl affords a racemic adduct and is accompanied by racemization of the unreacted chiral ester. In the presence of benzoyl peroxide, the reaction proceeds similarly, but no racemization of the starting chiral ester occurs.

inorganic chemicalschemistry.chemical_compoundChemistryorganic chemicalsmedicineOrganic chemistryGeneral ChemistryBenzoyl peroxideMedicinal chemistryRacemizationIron pentacarbonylAdductmedicine.drugRussian Chemical Bulletin
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Intramolecular cyclization of chloral allyl hemiacetal under the action of the Fe(CO)5-DMF system

1999

Chloral allyl hemiacetal undergoes cyclization in the presence of the Fe(CO)5-DMF system to form 3,3,5-trichloro-2-hydroxytetrahydropyran rather than a butyrolactone derivative.

chemistry.chemical_compoundChemistryIntramolecular cyclizationHemiacetalChloralGeneral ChemistryMedicinal chemistryDerivative (chemistry)Russian Chemical Bulletin
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ChemInform Abstract: Intramolecular Cyclization of Chloral Allyl Hemiacetal under the Action of the Fe(CO)5-DMF System.

2010

Chloral allyl hemiacetal undergoes cyclization in the presence of the Fe(CO)5-DMF system to form 3,3,5-trichloro-2-hydroxytetrahydropyran rather than a butyrolactone derivative.

chemistry.chemical_compoundchemistryIntramolecular cyclizationChloralHemiacetalOrganic chemistryGeneral MedicineMedicinal chemistryDerivative (chemistry)ChemInform
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