6533b7d1fe1ef96bd125caa0
RESEARCH PRODUCT
Difference in the behavior of methyl (S)-?-bromopropionate in its addition to trimethylvinylsilane depending on the method of initiation
S. A. OrlovaAlexander B. TerentievTamara T. VasilievaErkki KolehmainenKatri LaihiaYu. N. BelokonE. I. MysovN. S. IkonnikovN. A. Kuz'minasubject
inorganic chemicalschemistry.chemical_compoundChemistryorganic chemicalsmedicineOrganic chemistryGeneral ChemistryBenzoyl peroxideMedicinal chemistryRacemizationIron pentacarbonylAdductmedicine.drugdescription
The addition of methyl (S)-2-bromopropionate to trimethylvinylsilane initiated by systems based on iron pentacarbonyl affords a racemic adduct and is accompanied by racemization of the unreacted chiral ester. In the presence of benzoyl peroxide, the reaction proceeds similarly, but no racemization of the starting chiral ester occurs.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1996-03-01 | Russian Chemical Bulletin |