6533b7d7fe1ef96bd1268d3d

RESEARCH PRODUCT

Detection and correction of interferences in spectroscopy techniques

A.r Maurı́M LlobatD Adriá

subject

Phenol redAnalyteSignal processingAnalytical chemistryBiochemistryAnalytical ChemistryChemometricschemistry.chemical_compoundchemistryBromothymol blueMethyl orangeEnvironmental ChemistryBromocresol purpleSpectroscopySpectroscopy

description

By combining the apparent content curves method and the Youden method, we have developed a strategy for detecting constant and proportional errors in spectroscopy techniques. A method for elimination of spectral interferences (different of blank) is also proposed. To apply of this method there must be a matrix effect that varies with the amount of sample or a simulated matrix effect provided working under different experimental conditions that induce a variation of the analytical signal of the analyte. The proposed procedures have been applied to the determination of methyl orange in presence of phenol red, bromothymol blue and bromocresol purple.

https://doi.org/10.1016/s0003-2670(00)01166-1