6533b7d8fe1ef96bd12696ec
RESEARCH PRODUCT
Reductive transformations - 11. stereoselective cycloannelation and bridging of the cyclooctatetraene dianionMakromol. Chem., Rapid. Commun. 1988, 9, in press.
Klaus MüllenGünter Krummelsubject
chemistry.chemical_classificationAnnulationStereochemistryOrganic ChemistryHalocarbonBiochemistrychemistry.chemical_compoundCyclooctatetraenePolycyclic compoundchemistryDrug DiscoveryElectrophileStereoselectivityBifunctionalAliphatic compounddescription
Abstract Bifunctional electrophiles with C4-, C6-, and C8-chains are reacted with the cyclooctatetraene dianion to selectively give novel cycloannelation and bridging products which possess a surprising stereochemistry and are useful starting compounds for further syntheses.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1988-01-01 | Tetrahedron Letters |