6533b7d8fe1ef96bd126975b
RESEARCH PRODUCT
One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
Irene C. LazzariniPablo AlborésEva RentschlerLuca M. Carrellasubject
Schiff baseHydrogen bondLigandStereochemistryExchange interaction02 engineering and technologyZero field splitting010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMaterials ChemistryCarboxylatePhysical and Theoretical Chemistry0210 nano-technologydescription
Abstract We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of this complex, densely packed through C–H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-11-01 | Inorganica Chimica Acta |