6533b7d8fe1ef96bd126ac66
RESEARCH PRODUCT
Complexes of organometallic compounds
Rosario BoscoRosalba Cefalùsubject
Inorganic ChemistryBipyramidStereochemistryChemistryOrganic ChemistryMaterials ChemistryMoleculeMoietyTrigonal crystal systemTrigonal structurePhysical and Theoretical ChemistryBiochemistryGroup 2 organometallic chemistrydescription
Abstract A number of novel compounds of dimethyllead(IV) and diphenyllead(IV) moieties with ligands having a rigid geometry when coordinating, have been prepared and characterized. The goal of the work was the building of model molecules for five-coordinated R 2 Pb IV , with known configuration of the CPbC skeleton. From spectroscopic data it is inferred that the complexes under investigation have a distorted bipyramidal trigonal structure, with the CPbC moiety allocated in the trigonal plane.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1971-01-01 | Journal of Organometallic Chemistry |