6533b7d8fe1ef96bd126ae50

RESEARCH PRODUCT

[Et4N][7-Me2S-nido-B11H12]

Clara ViñasFrancesc TeixidorJonathan BouldRaikko KivekäsReijo Sillanpää

subject

biology010405 organic chemistryPrecipitation (chemistry)ChemistryInorganic chemistryGeneral MedicineCrystal structure010402 general chemistry01 natural sciencesChlorideMedicinal chemistryGeneral Biochemistry Genetics and Molecular Biology0104 chemical sciencesDeprotonationmedicinebiology.proteinMoleculemedicine.drugOrganic anion

description

Tetraethylammonium 7-dimethylsulfanyl-nido-dodecahydroundecaborate, [Et(4)N][7-Me(2)S-nido-B(11)H(12)] or C(8)H(20)N(+).C(2)H(18)B(11)S(-), is a product of the deprotonation of [7-Me(2)S-nido-B(11)H(13)] with KHBEt(3) and precipitation with tetraethylammonium chloride. The effect of removing one endo-terminal H atom is to cause a general contraction of the open-face B-B distances.

https://doi.org/10.1107/s010827010300698x