6533b7d8fe1ef96bd126b84e

RESEARCH PRODUCT

Thermal and light induced polymorphism in iron(II) spin crossover compounds.

Amber L. ThompsonAna GaletM. Carmen MuñozJosé Antonio RealAndrés E. Goeta

subject

Spin statesCondensed matter physicsUNESCO::QUÍMICA::Química inorgánicaChemistryUNESCO::QUÍMICAIronMetals and AlloysInduced Polymorphism ; Iron ; Spinchemistry.chemical_elementInduced PolymorphismGeneral Chemistry:QUÍMICA::Química inorgánica [UNESCO]:QUÍMICA [UNESCO]CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographySpinPolymorphism (materials science)Spin crossoverThermalMaterials ChemistryCeramics and CompositesLight inducedBoron

description

The spin crossover complexes {Fe[H2B(pz)2]2L} ([H2B(pz)2]2 = dihydrobis(pyrazolyl)borate, L = 2,2'-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for 2 are different from that of the thermally induced high spin state and from those of 1. Real Cabezos, Jose Antonio, Jose.A.Real@uv.es

yearjournalcountryeditionlanguage
2004-01-01
http://hdl.handle.net/10550/16795