6533b7d9fe1ef96bd126b975
RESEARCH PRODUCT
Multielectron oxidation in a ferromagnetically coupled dinickel(ii) triple mesocate.
Hong-cai ZhouMaría CastellanoJoan CanoOscar FabeloJesús Ferrando-soriaStephen Fordhamsubject
LigandStereochemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistryRedoxCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonNickelCrystallographychemistryMaterials ChemistryCeramics and Compositesdescription
Triple-stranded dinuclear nickel(ii) complexes of the meso-helicate type have been obtained from the new N,N'-1,3-phenylenebis(pyrazine-2-carboxamidate) ligand; they possess a multielectron redox behaviour featuring up to four stepwise, one-electron oxidation reactions of the two ferromagnetically coupled Ni(II) ions to afford the putative high-valent dinickel(iii) and dinickel(iv) species, as supported by theoretical calculations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-07-25 | Chemical communications (Cambridge, England) |