Author: Stephen Fordham

0000000000331469

AUTHOR

Stephen Fordham

Multielectron oxidation in a ferromagnetically coupled dinickel(ii) triple mesocate.

Triple-stranded dinuclear nickel(ii) complexes of the meso-helicate type have been obtained from the new N,N'-1,3-phenylenebis(pyrazine-2-carboxamidate) ligand; they possess a multielectron redox behaviour featuring up to four stepwise, one-electron oxidation reactions of the two ferromagnetically coupled Ni(II) ions to afford the putative high-valent dinickel(iii) and dinickel(iv) species, as supported by theoretical calculations.

research product

CCDC 1045153: Experimental Crystal Structure Determination

Related Article: Jesús Ferrando-Soria, Oscar Fabelo, María Castellano, Joan Cano, Stephen Fordham, Hong-Cai Zhou|2015|Chem.Commun.|51|13381|doi:10.1039/C5CC03544A

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