6533b7d9fe1ef96bd126c007
RESEARCH PRODUCT
false
Klaus MühlbachRolf C. Schulzsubject
chemistry.chemical_compoundEnd-groupAnionic addition polymerizationchemistryEndcappingPolymer chemistryCopolymerCationic polymerizationOrganic chemistryPolystyreneLiving cationic polymerizationOctanedescription
By endcapping of living polystyrene with ethylene oxide and subsequent reaction with bromoacetyl bromide a polymer with a bromoacetoxy endgroup was obtained. This was used as a macroinitiator for the living cationic polymerization of 1-azabicyclo[4.2.0]octane. The structure and composition of the so formed two-block copolymer was elucidated by different methods. The ratio of the two block and their lengths were varied within broad limits.
year | journal | country | edition | language |
---|---|---|---|---|
1989-10-01 | Die Makromolekulare Chemie |