6533b7d9fe1ef96bd126c05a
RESEARCH PRODUCT
Bismuth trihalide complexes with nitrogen and phosphorus chelating ligands
M. ConsiglioGiuseppe AlonzoC. PretiNuccio Bertazzisubject
Inorganic chemistryTrihalideHalidechemistry.chemical_elementInfrared spectroscopyBismuthInorganic Chemistrychemistry.chemical_compoundchemistryHalogenMaterials ChemistryMass spectrumMethanolPhysical and Theoretical ChemistryStoichiometrydescription
Abstract Bismuth(III) halides react with 1,10-phenanthroline, 2-pyridinecarboxaldehyde-2-pyridylhydrazone and diphenylphosphynoethane in methanol. A stoichiometry differing from 1:1 is found only for BiCl 3 (Phen) 1.33 and BiCl 3 (Dpe) 1.5 . Characterization of these compounds, which are not very soluble in common solvents, follows from analytical, mass and IR spectral data. In the low frequency region, the IR spectra proved to be useful to ascertain the presence of bridging halogens.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1985-11-01 | Inorganica Chimica Acta |