6533b7d9fe1ef96bd126c0c3
RESEARCH PRODUCT
Synthesis and characterization of novel organic–inorganic hybrid block copolymers
Do Y. YoonKook Ji KimPatrick Theatosubject
Contact angleThermogravimetryMaterials sciencePolymerizationNanoporousAtom-transfer radical-polymerizationPolymer chemistryThermal decompositionCopolymerGeneral Physics and AstronomyPhysical and Theoretical ChemistryHybrid materialdescription
Novel organic–inorganic hybrid block copolymers based on poly(methylsilsesquioxanes) (PMSSQs) have been synthesized. Two routes to functionalized PMSSQs are presented and from both atom transfer radical polymerization of methylmethacrylate could be performed. Copolymers with different block ratios have been polymerized and were characterized. In particular, thermal properties were investigated by TGA and the promising thermal decomposition behaviour makes the copolymers potential candidates as pore generators in future nanoporous materials. Additionally, these copolymers were analysed as surface coatings of regular PMMA. Contact angle measurements proved the dramatic effect on the surface properties of such modified PMMA.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-01-01 | Phys. Chem. Chem. Phys. |