Polymer-supported molybdenyl thioglycolate as oxygen atom transfer reagent

6533b7d9fe1ef96bd126c0d5

RESEARCH PRODUCT

Polymer-supported molybdenyl thioglycolate as oxygen atom transfer reagent

Pedro Palanca Salvador Gil V. Sanz Pau Arroyo Amalia Muñoz Joaquin Sanchis

subject

Process Chemistry and Technology Substrate (chemistry)Photochemistry Catalysis Catalysis chemistry.chemical_compound chemistry Benzoin Reagent Yield (chemistry)Pyridine Benzil Physical and Theoretical Chemistry Butanethiol

description

Abstract Oxo-transfer reactions of a variety of substrates in DMF or methanol using polymer-supported molybdenyl thioglycolate (PSMT) have been investigated. The clean oxidation of Me 2 PhP, n -butanethiol or benzoin to yield Me 2 PhPO, disulfide or benzil, respectively, occurs in high yield. In the presence of air or pyridine N-oxide, a catalytic cycle is accomplished which goes on until the completion of the substrate.

year	journal	country	edition	language
2000-10-01	Journal of Molecular Catalysis A: Chemical

https://doi.org/10.1016/s1381-1169(00)00271-5

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