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RESEARCH PRODUCT
Complexes of organometallic compounds
Antonio GianguzzaRosalba CefalùLorenzo PelleritoRenato Barbierisubject
Magnetic measurementsChemistryOrganic ChemistryInorganic chemistrychemistry.chemical_elementBiochemistryMedicinal chemistryElectron spectroscopyAdductInorganic ChemistryNickelOctahedronMössbauer spectroscopyMaterials ChemistryPhysical and Theoretical ChemistryTinGroup 2 organometallic chemistrydescription
Abstract Novel 1/1 adducts have been obtained from the complex N , N ′-ethylenebis(salicylideneiminato)nickel(II) (NiSalen) with di- and mono-organotin(IV) chlorides, and their solid state configuration investigated by Mossbauer , IR and electronic spectroscopy and magnetic measurements. In coordinated NiSalen the square planar structure is maintained around Ni II , and the coordination to tin involves three-coordinate phenolic oxygens. The environment of Sn IV is judged to be octahedral in both types of compounds. A trans -R 2 , cis -Cl 2 configuration is advanced for R 2 SnCl 2 NiSalen.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1974-04-01 | Journal of Organometallic Chemistry |