Stereoselective synthesis of the naturally occurring 2-pyranone dodoneine

6533b7d9fe1ef96bd126cd17

RESEARCH PRODUCT

Stereoselective synthesis of the naturally occurring 2-pyranone dodoneine

Juan Murga Paula ÁLvarez-bercedo Miguel Carda Eva Falomir J. Alberto Marco

subject

Allylation Stereochemistry Chemistry Organic Chemistry Enantioselective synthesis Total synthesis Asymmetric synthesis Ring (chemistry)Metathesis 5 6-Dihydropyran-2-ones Stereocenter Dodoneine Ring-closing metathesis Oxygen heterocycles Stereoselectivity Ring-closing metathesis Physical and Theoretical Chemistry

description

The first total synthesis of the naturally occurring dihydropyranone dodoneine is reported. Asymmetric allylation reactions were used for the stereoselective generation of the two stereogenic centers. The pyranone ring was created by ring-closing metathesis. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

year	journal	country	edition	language
2008-08-01

http://hdl.handle.net/10234/22304

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