6533b7d9fe1ef96bd126cefe
RESEARCH PRODUCT
X-ray crystal structures of copper(II) and cobalt(II) complexes with Schiff base ligands. Reactivity towards dioxygen
Arie Van Der LeeCatherine ReyéJan SýkoraRobert J. P. CorriuFrancis CarréEmmanuelle Lancelle-beltranRoger GuilardAhmad Mehdisubject
Schiff base010405 organic chemistryLigandInorganic chemistrychemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciencesCopper3. Good health0104 chemical sciencesAdductInorganic ChemistryMetalchemistry.chemical_compoundchemistryvisual_artPolymer chemistryvisual_art.visual_art_medium[CHIM.CRIS]Chemical Sciences/Cristallography[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Reactivity (chemistry)CobaltMOLECULAR-STRUCTUREdescription
Copper(II) and cobalt(II) Schiff base complexes with derivatives of the pentadentate ligand bis(salicylideneimino-3-propyl)amine [H2salDPT] have been prepared. The X-ray crystal structures of the copper(II) complexes Cu[salDPT] and Cu[sal(n-propyltrimethylsilyl)DPT] were determined and revealed five-coordination at the metal centre in both cases. The 1 ∶ 1 dioxygen adduct of Co[sal(n-propyltrimethylsilyl)DPT] was also isolated and its X-ray molecular structure determined.
year | journal | country | edition | language |
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2003-01-01 |