6533b7d9fe1ef96bd126d516
RESEARCH PRODUCT
Cardopatine and isocardopatine, two novel cyclobutane substances from Cardopatium corymbosum
Alberto ArnoneRosanna MondelliAntonio SelvaLiliana LamartinaSalvatore PetrusoSalvatore PlesciaVincenzo SprioLeofoldo Ceraulosubject
chemistry.chemical_compoundMonomerchemistryStereochemistryMass spectrumCardopatium corymbosumPlant ScienceGeneral MedicineHorticultureMolecular BiologyBiochemistryCis–trans isomerismCyclobutanedescription
Two new natural substances containing a cyclobutane unit, cardopatine and isocardopatine, the trans and cis isomers respectively of 5,5″ (cyclobut-1,2-ylene-diethynylene)bis 2,2′-bithiophene), together with the known α-terthienyl and 5-(but-3-en-1-ynyl)-2,2′-bithienyl, have been isolated from the roots of Cardopatium corymbosum. Evidence is given that the novel cyclobutane substances are not the products of a spontaneous dimerization of a bithienyl monomeric unit. Structure determination and conformational analysis are reported.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1978-01-01 | Phytochemistry |