6533b7d9fe1ef96bd126d6ad
RESEARCH PRODUCT
Catalytic enantioselective addition of terminal alkynes to aromatic aldehydes using zinc-hydroxyamide complexes
Alicia Marco‐aleixandreGonzalo BlayJosé R. PedroIsabel FernándezLuz CardonaM. Carmen Muñozsubject
chemistry.chemical_classificationLigandArylOrganic ChemistryEnantioselective synthesischemistry.chemical_elementZincBiochemistryCatalysischemistry.chemical_compoundchemistryFISICA APLICADAReagentOrganic chemistryPhysical and Theoretical ChemistryAlkylMandelamidedescription
[EN] A mandelamide ligand, derived from (S)-mandelic acid and (S)-phenylethanamine, catalyzes the addition of aryl-, alkyl-and silyl-alkynylzinc reagents to aromatic and heteroaromatic aldehydes with good yields and good to high enantioselectivities.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-01-01 | Organic & Biomolecular Chemistry |