ChemInform Abstract: Enantiocontrol in the Intermolecular Cyclopropanation Reaction Catalyzed by Dirhodium(II) Complexes with ortho-Metalated Aryl Phosphine Ligands.

6533b7dafe1ef96bd126dfd4

RESEARCH PRODUCT

ChemInform Abstract: Enantiocontrol in the Intermolecular Cyclopropanation Reaction Catalyzed by Dirhodium(II) Complexes with ortho-Metalated Aryl Phosphine Ligands.

Pascual Lahuerta Julia Pérez-prieto Mario Barberis Mercedes Sanau

subject

chemistry.chemical_compound Ethyl diazoacetate Chemistry Cyclopropanation Aryl Intermolecular force Enantioselective synthesis General Medicine Medicinal chemistry Phosphine Catalysis

description

(P) and (M) dirhodium(II) complexes with ortho-metalated aryl phosphines are assessed as chiral catalysts in the enantioselective cyclopropanation of styrenes by ethyl diazoacetate; enantioselectivities up to 91% and up to 87%, respectively, for cis- and trans-2-arylcyclopropanecarboxylates are observed.

year	journal	country	edition	language
2010-05-25	ChemInform

https://doi.org/10.1002/chin.200128106

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