Studien zum Vorgang der Wasserstoffübertragung, 18. Hydrierende Spaltung cyclischer quartärer Ammoniumsalze und einiger Verbindungen mit Brom am Brückenkopf Kernhydrierung von Pyridiniumsalzen und Desoxygenierung einiger N ‐Oxide

6533b7dafe1ef96bd126e0b6

RESEARCH PRODUCT

Studien zum Vorgang der Wasserstoffübertragung, 18. Hydrierende Spaltung cyclischer quartärer Ammoniumsalze und einiger Verbindungen mit Brom am Brückenkopf Kernhydrierung von Pyridiniumsalzen und Desoxygenierung einiger N ‐Oxide

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

In einer Variante der Emmert-Spaltung werden die cyclischen Ammoniumsalze 1a–c unter Ringoffnung in 2a–c, ubergefuhrt. – Pyridiniumsalze liefern in wasriger Salzsaure N-substituierte Piperidinderivate. N-Oxide werden zu tert. Aminen desoxygeniert; am Bruckenkopf gebundenes Brom wird elektrolytisch sehr leicht durch Wasserstoff ersetzt.

year	journal	country	edition	language
1968-12-01	Chemische Berichte

https://doi.org/10.1002/cber.19681011217

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