Selective Metal–Ligand Bond-Breaking Driven by Weak Intermolecular Interactions: From Metamagnetic Mn(III)-Monomer to Hexacyanoferrate(II)-Bridged Metamagnetic Mn2Fe Trimer

6533b7dafe1ef96bd126e963

RESEARCH PRODUCT

Selective Metal–Ligand Bond-Breaking Driven by Weak Intermolecular Interactions: From Metamagnetic Mn(III)-Monomer to Hexacyanoferrate(II)-Bridged Metamagnetic Mn2Fe Trimer

Abhishikta Chatterjee Somen Goswami Antonio Frontera Rajat Saha Rajat Saha Subrata Kumar Dey Indrajit Saha Sanjay Kumar Carlos J. Gómez García Soumen Singha

subject

010405 organic chemistry Ligand Intermolecular force Hexacyanoferrate II Trimer Bond breaking 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound Crystallography Monomer chemistry visual_art visual_art.visual_art_medium Physical and Theoretical Chemistry

description

Metal–ligand coordination interactions are usually much stronger than weak intermolecular interactions. Nevertheless, here, we show experimental evidence and theoretical confirmation of a very rare...

year	journal	country	edition	language
2020-05-28	Inorganic Chemistry

https://doi.org/10.1021/acs.inorgchem.0c00909

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