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RESEARCH PRODUCT
Optical sensing of cyanide using hybrid biomolecular films
Emilio PalomaresEmmanuel TopoglidisJames R. DurrantKeira Polandsubject
biologyCyanideInorganic chemistryBiomaterialNanoparticleBioinorganic chemistryPhotochemistryCofactorInorganic Chemistrychemistry.chemical_compoundchemistryMaterials Chemistrybiology.proteinsense organsHemoglobinPhysical and Theoretical ChemistryMesoporous materialHemedescription
The selective sensing of cyanide anions in water has been studied using a hybrid biomaterial composed of a mesoporous TiO2 film of crystalline nanoparticles and the protein hemoglobin. The mesoporous structure of the film prevents protein unfolding and also stabilizes the oxidized form of the prosthetic groups. Low-levels of cyanide anions (<0.2 ppm (0.2 mgr/L)) can be detected by monitoring the changes in the optical properties of the hybrid biomolecular films upon cyanide binding to the heme groups.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-12-01 | Inorganic Chemistry Communications |