6533b7dafe1ef96bd126ec78
RESEARCH PRODUCT
Bis(cyclohexylammonium) tetrachlorido(oxalato)stannate(IV)
Waly DialloModou SarrLaurent PlasseraudAminata Diasse-sarrHélène Catteysubject
Metal-Organic Paperschemistry.chemical_classificationCoordination sphereStannatebiologyCyclohexane conformationSalt (chemistry)General ChemistryCondensed Matter Physicsbiology.organism_classificationMedicinal chemistrylcsh:Chemistrychemistry.chemical_compoundchemistrylcsh:QD1-999TetraMoietyGeneral Materials ScienceAmmoniumChelationdescription
The title salt, (C6H14N)2[Sn(C2O4)Cl4], was obtained as a by-product from the reaction between 2C6H14N+·C2O42−·1.5H2O and SnCl2·2H2O. The cyclohexylammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl4 moiety, resulting in a distorted octahedral coordination sphere of the SnIV atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N—H...O and N—H...Cl interactions into a layered arrangement parallel to (100).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-07-27 | Acta Crystallographica Section E |