6533b7dafe1ef96bd126ef52
RESEARCH PRODUCT
Oxidovanadium(v) complexes with l-proline-based amino acid phenolates
Pasi SalonenAnssi PeuronenJari SinkkonenAri Lehtonensubject
amino acidsfenolitvanadiumcoordination complexeskompleksiyhdisteetphenolsaminohapotvanadiinidescription
L-proline was used to prepare chiral, tridentate amino acid phenol proligands H2L1—4. These proligands react with vanadium precursors VO(acac)2, VOSO4 ∙ 5 H2O and VO(OPr)3 in methanol to form the corresponding oxidoalkoxidovanadium(V) complexes 1—4. The complexes crystallize from methanol, and are octahedrally coordinated with a general formula [VO(L1—4)(OMe)(MeOH)]. In solution, however, they adopt several different conformations or isomeric structures depending on the solvent. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-01-01 |