Studien zum Ablauf der Substitution, XVIII Über die Einwirkung von Carbonsäureanhydriden auf Sulfoxyde

6533b7dafe1ef96bd126f502

RESEARCH PRODUCT

Studien zum Ablauf der Substitution, XVIII Über die Einwirkung von Carbonsäureanhydriden auf Sulfoxyde

subject

Chemistry Organic Chemistry Physical and Theoretical Chemistry Medicinal chemistry

description

Aliphatische Sulfoxyde setzen sich bereits bei Raumtemperatur mit Essigsaure- oder Benzoesaureanhydrid zu den entsprechenden α-Acyloxy-thioathern um. Im Falle von Methyl-phenyl-, Phenyl-benzyl–und Dibenzyl-sulfoxyd sind Temperaturen uber 100° erforderlich.—α-Acyloxy-thioather konnen Saure unter Bildung eines Olefins abspalten; sie konnen aber auch bei hoherer Temperatur in Aldehyd und S-acyliertes Mercaptan zerfallen.

year	journal	country	edition	language
1959-08-12	Justus Liebigs Annalen der Chemie

https://doi.org/10.1002/jlac.19596260103

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