6533b7dafe1ef96bd126f50e
RESEARCH PRODUCT
Organolanthanides as single component homogeneous catalysts for isoprenehex—1-ene co-polymerisation
Denise Barbier-baudryPascale DesmursAlain Dormondsubject
chemistry.chemical_compoundchemistryPolymerizationDienePolymer chemistryCopolymerHomogeneous catalysisGeneral ChemistryMetalloceneEne reactionIsopreneCatalysisdescription
Abstract Bisallylansalanthanide complexes act as single component catalysts of diene polymerisation; from an equimolar mixture of isoprene and hex-1-ene, a co-polymer hex-1-ene/isoprene = 1:10 is obtained, this copolymer is essentially formed of 1,4- trans polyisoprene blocks separated by only one inserted hexyl group.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-07-01 | Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry |