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RESEARCH PRODUCT

Synergistic effects of multiwalled carbon nanotubes and Al on the electrochemical hydrogen storage properties of Mg2Ni-type alloy prepared by mechanical alloying

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Abstract Mg 2− x Al x Ni ( x  = 0, 0.25) electrode alloys with and without multiwalled carbon nanotubes (MWCNTs) have been prepared by mechanical alloying (MA) under argon atmosphere at room temperature using a planetary high-energy ball mill. The microstructures of synthesized alloys are characterized by XRD, SEM and TEM. XRD analysis results indicate that Al substitution results in the formation of AlNi-type solid solution that can interstitially dissolve hydrogen atoms. In contrast, the addition of MWCNTs hardly affects the XRD patterns. SEM observations show that after co-milling with 5 wt. % MWCNTs, the particle sizes of both Mg 2 Ni and Mg 1.75 Al 0.25 Ni milled alloys are decreased explicitly. The TEM images reveal that ball milling is a good method to cut long MWCNTs into short ones. These MWCNTs aggregate along the boundaries and surfaces of milled alloy particles and play a role of lubricant to weaken the adhesion of alloy particles. The majority of MWCNTs retain their tubular structure after ball milling except a few MWCNTs whose tubular structure is destroyed. Electrochemical measurements indicate that all milled alloys have excellent activation properties. The Mg 1.75 Al 0.25 Ni-MWCNTs composite shows the highest discharge capacity due to the synergistic effects of MWCNTs and Al on the electrochemical hydrogen storage properties of Mg 2 Ni-type alloy. However, the improvement on the electrode cycle stability by adding MWCNTs is unsatisfactory.