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RESEARCH PRODUCT
ChemInform Abstract: Photoinduced Functionalization of the C-20 Methyl Group of the Nor-diterpene Atractyligenin.
Nicolò VivonaSilvestre BuscemiMaurizio BrunoSergio RosselliFranco Piozzisubject
Terpenechemistry.chemical_compoundDecarboxylationChemistryStereochemistrySurface modificationGeneral MedicineMethanolDiterpeneAtractyligeninMethyl groupdescription
Abstract Irradiation of the nor-diterpene atractyligenin at λ =254 nm in methanol gave, on one hand, the decarboxylation product, and provided, on the other hand, the transformation of the C-20 angular methyl into a methylene-carbomethoxy group. A photochemical pathway involving formation of C-19/C-20 bond is suggested.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-05-22 | ChemInform |