Multicatalytic Transformation of (Meth)acrylic Acids: a One-Pot Approach to Biobased Poly(meth)acrylates

6533b7dbfe1ef96bd127150d

RESEARCH PRODUCT

Multicatalytic Transformation of (Meth)acrylic Acids: a One-Pot Approach to Biobased Poly(meth)acrylates

Wei Qiang Vincent Placet Carine Robert Hugo Fouilloux Christophe M. Thomas

subject

[CHIM.POLY] Chemical Sciences/Polymers 010402 general chemistry 7. Clean energy 01 natural sciences Catalysis Acylation chemistry.chemical_compound Copolymer Organic chemistry chemistry.chemical_classification [CHIM.ORGA]Chemical Sciences/Organic chemistry 010405 organic chemistry [CHIM.CATA] Chemical Sciences/Catalysis General Chemistry Polymer Meth-[CHIM.CATA]Chemical Sciences/Catalysis General Medicine [PHYS.MECA]Physics [physics]/Mechanics [physics][CHIM.ORGA] Chemical Sciences/Organic chemistry 0104 chemical sciences Monomer Petrochemical [CHIM.POLY]Chemical Sciences/Polymers chemistry Polymerization [PHYS.MECA] Physics [physics]/Mechanics [physics]Renewable resource

description

International audience; Shifting from petrochemical feedstocks to renewable resources can address some of the environmental issues associated with petrochemical extraction and make plastics production sustainable. Therefore, there is a growing interest in selective methods for transforming abundant renewable feedstocks into monomers suitable for polymer production. Reported herein are one-pot catalytic systems, that are active,<br&gtproductive, and selective under mild conditions for the synthesis of copolymers from renewable materials. Each system allows for anhydride formation, alcohol acylation and/or acid esterification, as well as polymerization of the formed (meth)- acrylates, providing direct access to a new library of unique poly(meth)acrylates.

year	journal	country	edition	language
2021-07-19

https://hal.archives-ouvertes.fr/hal-03427031/document

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