6533b7dcfe1ef96bd12716b8

RESEARCH PRODUCT

The cyclic [N(PiPr2E)2]+ (E = Se, Te) cations: a new class of inorganic ring system.

Heikki M. TuononenJari KonuTristram Chivers

subject

chemistry.chemical_classificationStereochemistryIodideMetals and Alloyschemistry.chemical_elementliganditGeneral ChemistryRing (chemistry)IodineMedicinal chemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsdikalkogenoimidodifosfinaatitdichalcogenoimidodiphosphinateschemistryMaterials ChemistryCeramics and Composites

description

The two-electron oxidation of [(tmeda)NaN(PiPr2E)2] with iodine produces the cyclic [N(PiPr2E)2]+ (E = Se, Te) cations, which exhibit long E–E bonds in the iodide salts. peerReviewed

10.1039/b600040ahttps://pubmed.ncbi.nlm.nih.gov/16583003