6533b7dcfe1ef96bd1271e99

RESEARCH PRODUCT

Self-Assembly of Colloidal Molecules due to Self-Generated Flow.

Thomas PalbergThomas SpeckRan Niu

subject

PhysicsCondensed Matter - Materials ScienceRange (particle radiation)FusionSolvent flowMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesGeneral Physics and Astronomy02 engineering and technologyCondensed Matter - Soft Condensed Matter021001 nanoscience & nanotechnology01 natural sciencesSymmetry (physics)ColloidClassical mechanicsFlow (mathematics)Chemical physics0103 physical sciencesSoft Condensed Matter (cond-mat.soft)MoleculeSelf-assembly010306 general physics0210 nano-technology

description

The emergence of structure through aggregation is a fascinating topic and of both fundamental and practical interest. Here we demonstrate that self-generated solvent flow can be used to generate long-range attractions on the colloidal scale, with subpiconewton forces extending into the millimeter range. We observe a rich dynamic behavior with the formation and fusion of small clusters resembling molecules. The dynamics of this assembly is governed by an effective conservative energy that for large separations r decays as 1/r. Breaking the flow symmetry, these clusters can be made active.

10.1103/physrevlett.119.028001https://pubmed.ncbi.nlm.nih.gov/28753375