6533b7dcfe1ef96bd1272794

RESEARCH PRODUCT

Single-crystal EPR study of the bimetallic ferrimagnetic chain MnCu(EDTA)·6H2O

Claudia ZanchiniEugenio CoronadoJuan J. Borrás-almenarDante Gatteschi

subject

Chemistrychemistry.chemical_elementManganeseCopperlaw.inventionInorganic ChemistryLaser linewidthCrystallographyDipoleNuclear magnetic resonancelawFerrimagnetismMaterials ChemistryPhysics::Atomic PhysicsPhysical and Theoretical ChemistryElectron paramagnetic resonanceBimetallic stripSingle crystal

description

Abstract A single-crystal EPR study of the bimetallic chain compound MnCu(EDTA)·6H2O is reported. The angular dependence of the linewidth is discussed in relation to the magnetic dipole-dipole interaction, manganese zerofield splitting (ZFS) and copper hyperfine coupling. The calculation of the second moments indicates that ZFS is comparable to the dipolar contribution. The EPR data support the one-dimensional character of the compound.

yearjournalcountryeditionlanguage
1993-05-01Inorganica Chimica Acta
https://doi.org/10.1016/s0020-1693(00)91462-2