6533b7dcfe1ef96bd1273272
RESEARCH PRODUCT
A procedure for predicting sorption equilibrium in ternary polymer systems from Flory–Huggins binary interaction parameters and the inversion point of preferential solvation
Bernardo CeldaAugustín CamposClara M. GómezRafael GavaraRoberto Tejerosubject
chemistry.chemical_classificationPolymers and PlasticsChemistrySolvationBinary numberThermodynamicsSorptionPolymerFlory–Huggins solution theoryCondensed Matter PhysicsThermodynamic modelPolymer chemistryMaterials ChemistryChemical solutionPhysical and Theoretical ChemistryTernary operationdescription
A procedure has been developed, based on the Flory–Huggins theory as generalized by Pouchlý, which permits the calculation of preferential (λ) and total (Y) sorption coefficients from previous information on the binary interaction parameters, χ, χ, and g12(ϕ10) and on the mixture composition at which the sign of λ inverts. The expressions obtained were applied to 10 cosolvent polymer systems for which experimental values of λ and Y are known. Practically in all the studied systems, the theoretical predictions are in fair accordance with the experimental data.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1989-07-01 | Journal of Polymer Science Part B: Polymer Physics |