Phosphororganische Verbindungen, XV. Darstellung einiger neuer Phosphin‐ und Arsinalkylene

6533b7ddfe1ef96bd127523b

RESEARCH PRODUCT

Phosphororganische Verbindungen, XV. Darstellung einiger neuer Phosphin‐ und Arsinalkylene

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Triphenylphosphindichlorid und Triphenylarsindichlorid reagieren mit Malonester, Cyanessigester, Malonsauredinitril und Bis-benzolsulfonyl-methan in Gegenwart von Triathylamin zu bestandigen Derivaten des Triphenylphosphinmethylens bzw. Triphenylarsinmethylens. Aus Phenylnitromethan, Triphenylphosphindichlorid und Triphenylphosphin entsteht (uber Benzonitriloxyd als Zwischenprodukt) Benzonitril. Die UV-Spektren der dargestellten Verbindungen werden diskutiert.

year	journal	country	edition	language
1958-02-01	Chemische Berichte

https://doi.org/10.1002/cber.19580910234

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