Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene

6533b7ddfe1ef96bd1275482

RESEARCH PRODUCT

Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene

Claudio D'alfonso Claudio D'alfonso María González-béjar María González-béjar Geniece L. Hallett-tapley Emilio I. Alarcon Juan C. Scaiano Juan C. Scaiano Natalia L. Pacioni Christopher D. Mctiernan Osvaldo Lanzalunga

subject

Nanoparticle NANOCATALYSIS 010402 general chemistry Photochemistry 01 natural sciences Catalysis Catalysis Electron transfer chemistry.chemical_compound Materials Chemistry GOLD ISOMERIZATION 010405 organic chemistry Chemistry Otras Ciencias Químicas Ciencias Químicas Metals and Alloys General Chemistry Cis trans isomerization 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials AZOBENZENES Azobenzene Colloidal gold Ceramics and Composites Isomerization CIENCIAS NATURALES Y EXACTAS

description

Ablated, “pseudo-naked” gold nanoparticles (AuNPs) catalyze the cis–trans isomerization of substituted azobenzenes. para-Substitution was found to affect the rate of isomerization, suggesting the participation of AuNP-mediated electron transfer in the isomerization mechanism. Fil: Hallet Tapley, Geniece. University of Ottawa; Canadá Fil: D'Alfonso, Claudio. University of Ottawa; Canadá. Universita Di Roma; Italia Fil: Pacioni, Natalia Lorena. University of Ottawa; Canadá Fil: McTiernan, Cristopher D.. University of Ottawa; Canadá Fil: Gonzalez Bejar, Maria. University of Ottawa; Canadá. Universidad de Valencia; España Fil: Lanzalunga, Osvaldo. Universita Di Roma; Italia Fil: Alarcon, Emilio I.. University of Ottawa; Canadá Fil: Scaiano, Juan Cesar. University of Ottawa; Canadá. Universidad de Valencia; España

year	journal	country	edition	language
2013-01-01

10.1039/c3cc41669k http://hdl.handle.net/11573/525282

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