6533b7defe1ef96bd12766e3
RESEARCH PRODUCT
Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal–organic frameworks
Andrea PaceMaud SchwarzerC. G. PiscopoStefan LoebbeckeFederica TrapaniFederica TrapaniAngelos Polyzoidissubject
Materials Chemistry2506 Metals and AlloysChemistryOxygen storageChemistry (all)Inorganic chemistrychemistry.chemical_element02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesOxygenOxygen storage capacityNitrogenCatalysisCatalysi0104 chemical sciencesMaterials ChemistryFluorineMoietyOrganic chemistryMetal-organic framework0210 nano-technologyLinkerdescription
Two series of fluorine-containing UiO-66 have been synthesized, replacing the 1,4-benzodicarboxylic acid linker with increasing amounts of 2-fluoro-1,4-benzodicarboxylic acid or 2-trifluoromethyl-1,4-benzodicarboxylic acid. The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-10-01 | New Journal of Chemistry |