6533b81ffe1ef96bd1276f8c

RESEARCH PRODUCT

Total angular momenta of even-parity autoionizing levels and odd-parity high-lying levels of atomic uranium

Ikuo WakaidaChristopher GeppertKlaus WendtMasaki ObaMasabumi Miyabe

subject

Physicschemistry.chemical_elementIonic bondingUraniumCondensed Matter PhysicsPolarization (waves)Atomic and Molecular Physics and OpticsLaser linewidthsymbols.namesakeAutoionizationchemistryRydberg formulasymbolsRectangular potential barrierPhysics::Atomic PhysicsAtomic physicsSpectroscopy

description

Using three-step resonance ionization spectroscopy, over 200 even-parity autoionizing (AI) levels of atomic uranium, including Rydberg series converging to the second lowest ionic level (6L 11/2o), were observed in the 49 930–51 200 cm−1 energy range. Total angular momenta (J values) of these levels were determined by a polarization combination method as well as a method based on the J-momentum selection rule. Using the AI levels of which J values were determined unambiguously, unique J values were also assigned for about 70 high-lying odd-parity levels. The observed J-dependence on autoionization linewidth is interpreted as being due to a centrifugal potential barrier.

https://doi.org/10.1088/0953-4075/35/18/306