6533b81ffe1ef96bd127708a
RESEARCH PRODUCT
The dimerization of substituted 3-TMSO-1-alkynes with (φ3P)3RhCl
Thomas RüpingHellmut Singersubject
Inorganic ChemistrySteric effectschemistry.chemical_compoundChemistryPolymer chemistryMaterials ChemistryOrganic chemistryNuclear magnetic resonance spectroscopyPhysical and Theoretical ChemistryTriphenylphosphineAliphatic compoundCatalysisdescription
Abstract 3-Trimethylsilyloxy-1-alkynes were prepared from 3-hyroxy-1-alkynes and dimerized with (φ3P)3RhCl as a catalyst. The influence of a steric effect on the rates of dimerization is demonstrated.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1987-08-01 | Inorganica Chimica Acta |