Search results for "Triphenylphosphine"
showing 10 items of 168 documents
CCDC 731402: Experimental Crystal Structure Determination
2010
Related Article: C.A.Caputo, A.L.Brazeau, Z.Hynes, J.T.Price, H.M.Tuononen, N.D.Jones|2009|Organometallics|28|5261|doi:10.1021/om9006278
CCDC 671663: Experimental Crystal Structure Determination
2008
Related Article: J.L.Serrano, L.Garcia, J.Perez, E.Perez, J.Garcia, G.Sanchez, G.Lopez, I.J.S.Fairlamb, M.Liu|2008|Polyhedron|27|1699|doi:10.1016/j.poly.2008.02.001
CCDC 751043: Experimental Crystal Structure Determination
2010
Related Article: J.Vicente, I.Saura-Llamas, J.Turpin, D.Bautista, C.R.de Arellano, P.G.Jones|2009|Organometallics|28|4175|doi:10.1021/om9002895
CCDC 1828666: Experimental Crystal Structure Determination
2018
Related Article: Audrey Trommenschlager, Florian Chotard, Benoît Bertrand, Souheila Amor, Philippe Richard, Ali Bettaïeb, Catherine Paul, Jean-Louis Connat, Pierre Le Gendre, Ewen Bodio|2018|ChemMedChem|13|2408|doi:10.1002/cmdc.201800474
CCDC 671664: Experimental Crystal Structure Determination
2008
Related Article: J.L.Serrano, L.Garcia, J.Perez, E.Perez, J.Garcia, G.Sanchez, G.Lopez, I.J.S.Fairlamb, M.Liu|2008|Polyhedron|27|1699|doi:10.1016/j.poly.2008.02.001
CCDC 1429014: Experimental Crystal Structure Determination
2016
Related Article: Balasubramaniam Arul Prakasam, Anssi Peuronen, Manu Lahtinen, Manickavachagam Muruganandham, Erkki Kolehmainen, Esa Haapaniemi, Mika Sillanpää|2017|Polyhedron|123|453|doi:10.1016/j.poly.2016.11.027
CCDC 919694: Experimental Crystal Structure Determination
2013
Related Article: L.J.Farrugia, C.Evans, H.M.Senn, M.M.Hanninen, R.Sillanpaa|2012|Organometallics|31|2559|doi:10.1021/om2011744
On the Road to MM′X Polymers: Redox Properties of Heterometallic Ni···Pt Paddlewheel Complexes
2014
On the quest of heterometallic mixed-valence MM'X chains, we have prepared two stable discrete bimetallic compounds: the reduced (PPN)[ClNi(μ-OSCPh)4Pt] (PPN = bis(triphenylphosphine)iminium; OSCPh = benzothiocarboxylato) and the oxidized [(H2O)Ni(μ-OSCPh)4PtCl] species. The role of the aqua and chlorido axial ligands is crucial to facilitate oxidation of the {Ni(μ-OSCPh)4Pt} core. Experimental and theoretical analyses indicate that a NiPt-Cl/Cl-NiPt isomerization process occurs in the oxidized species. The electronic structure of the reduced system shows two unpaired electrons, one located in a d(x(2)-y(2)) orbital of the Ni(II) ion and a second in the antibonding d(z(2)-dz(2)) combination…
Electrochemical meso-functionalization of magnesium(II) porphine
2010
International audience; Regioselective meso-functionalization of the totally unsubstituted magnesium(II) porphine was performed by controlled potential electrolysis with pyridine and triphenylphosphine as nucleophiles leading to the original pyridinium and phosphonium substituted derivatives, respectively. The crystallographic structure of the latter is described as the only meso-phosphonium porphyrin reported to date.
Supramolecular Assembly of Organophosphonate Diesters Using Paddle-Wheel Complexes: First Examples in Porphyrin Series
2014
The reactions of dicopper tetrapivalate complex Cu2(μ-OOC-t-Bu)4(NCMe)2 (1) with triphenylphosphine oxide and diethyl phosphite allow paddle-wheel (PW) copper(II) complexes with phosphorus-containing axial ligands (2, 3) to be obtained. When meso-bis(diethoxyphosphoryl)porphyrins 4M were employed in this ligand exchange reaction, a series of one-dimensional (1D) homo- and heterometallic coordination polymers 5M composed of PW subunits and organophosphonate diesters were prepared and characterized by means of single crystal X-ray analysis. Planar porphyrinate 4Pd and nonplanar metalloporphyrinates 4Cu and 4Ni proved to be appropriate molecular structural blocks for assembly of coordination p…