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RESEARCH PRODUCT
Electrochemical meso-functionalization of magnesium(II) porphine
Charles H. DevillersAbdou K. D. DimeDominique LucasHélène Catteysubject
010405 organic chemistryMagnesiumMetals and AlloysRegioselectivitychemistry.chemical_elementGeneral Chemistry010402 general chemistryPhotochemistry01 natural sciencesPorphyrinCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundNucleophilechemistryPolymer chemistryPyridineMaterials ChemistryCeramics and Composites[CHIM.COOR]Chemical Sciences/Coordination chemistryPhosphoniumPyridiniumTriphenylphosphinedescription
International audience; Regioselective meso-functionalization of the totally unsubstituted magnesium(II) porphine was performed by controlled potential electrolysis with pyridine and triphenylphosphine as nucleophiles leading to the original pyridinium and phosphonium substituted derivatives, respectively. The crystallographic structure of the latter is described as the only meso-phosphonium porphyrin reported to date.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-12-08 |