6533b81ffe1ef96bd12770d4
RESEARCH PRODUCT
Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation
Joschua HelmerOlli J. PakkanenChris GendyAlexander HeppHeikki M. TuononenFelicitas Lipssubject
kemialliset sidoksetMaterials ChemistryMetals and AlloysCeramics and CompositesGeneral Chemistryheterosykliset yhdisteetCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialsdescription
Reductive debromination of the tribromoamidosilane 2 gave the tetracyclic silaheterocycle 3 through a unique reaction cascade involving unprecedented two-fold intramolecular cycloaddition by transient silylenes. Experimental and computational analyses of the reaction mechanism allowed the identification of the key intermediates that lead to the silaheterocycle 3 or, alternatively, to the cyclotrisilene 19. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2022-02-24 | Chemical Communications |