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RESEARCH PRODUCT
Electroorganic synthesis of nitriles via a halogen-free domino oxidation–reduction sequence
Siegfried R. WaldvogelMarius Franziskus Hartmersubject
NitrileMetals and AlloysHalogen freeNanotechnologySequence (biology)Oxidation reductionGeneral ChemistryCombinatorial chemistryCatalysisDominoSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundchemistryElectrodeMaterials ChemistryCeramics and CompositesMoietyGraphitedescription
A direct electroorganic sequence yielding nitriles from oximes in undivided cells is reported. Despite the fact that intermediate nitrile oxides might be formed, the method is viable to prepare benzonitriles without substituents ortho to the aldoxime moiety. This constant current method is easy to perform for a broad scope of substrates and employs common electrodes, such as graphite and lead.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-09-26 | Chemical Communications |