6533b81ffe1ef96bd12783a4

RESEARCH PRODUCT

Spectroscopy of XY5Z (C4v) Molecules: A Tensorial Formalism Adapted to the O(3) ⊃ Oh ⊃ C4v Chain

Vincent BoudonMaud RotgerMichel Loete

subject

PhysicsFormalism (philosophy of mathematics)OctahedronComputationMoleculePhysical and Theoretical ChemistrySpectroscopyMolecular physicsSpectroscopyAtomic and Molecular Physics and Optics

description

Abstract A tensorial formalism adapted to the case of XY 5 Z symmetric tops has been developed as an extension of the usual one for the octahedral molecules. We use the O (3) ⊃ O h ⊃ C 4 v group chain. All the coupling coefficients and formulas for the computation of matrix elements are given for this chain. Such relations are also deduced in the C 4 v group itself.

yearjournalcountryeditionlanguage
2000-03-01Journal of Molecular Spectroscopy
https://doi.org/10.1006/jmsp.1999.8034