6533b81ffe1ef96bd12783e1
RESEARCH PRODUCT
Synthesis and crystal structure of {Rh2(O2CCH3)4·P(o-CH3OH6H4)Ph2}2. A novel dirhodium(II) monoadduct with intermolecular μ-oxo interactions
Pascual LahuertaEduardo PerisSantiago García-grandaAngel AguirreF. Gómez-beltránM. A. UbedaC.j. Alarcónsubject
StereochemistryDimerIntermolecular forceSolid-stateCrystal structureMedicinal chemistryDirhodium tetraacetateInorganic ChemistryBond lengthchemistry.chemical_compoundchemistryAtomMaterials ChemistryPhysical and Theoretical ChemistryPhosphinedescription
Abstract We have investigated the reaction of dirhodium tetraacetate with the phosphine P( o -CH 3 OH 6 H 4 )Ph 2 (P) under different experimental conditions. From these reactions we have been able to isolate the dirhodium tetraacetate phosphine mono-adduct. The crystal structure shows that in the solid state this compound forms a centrosymmetric dimer of the dimer, {Rh 2 (O 2 CCH 3 ) 4 ·P(0-CH 3 OC 6 H 4 )Ph 2 } 2 , in which we oxygen atom from one acetate group in one Rh 2 (O 2 CCH 3 ) 4 ·P unit is axially coordinating one Rh atom on another Rh 2 (O 2 CCH 3 ) 4 · P unit (Rh⋯) 2.347(3) A intermolecular versus Rh⋯O 2.455(3) A intermolecular), and vice versa. The RhRh bond distance is 2.414(1) A while the intermolecular Rh⋯Rh distance is 3.45592) A.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1997-01-01 | Inorganica Chimica Acta |