Zur Kenntnis der o ‐Chinone, XIX. Hydrolysestudien an 2‐substituierten 1.3‐Dicarbonylverbindungen als Beitrag zum Mechanismus der Purpurogallinbildung

6533b81ffe1ef96bd1278433

RESEARCH PRODUCT

Zur Kenntnis der o ‐Chinone, XIX. Hydrolysestudien an 2‐substituierten 1.3‐Dicarbonylverbindungen als Beitrag zum Mechanismus der Purpurogallinbildung

Leopold Horner Dürckheimer Karl Heinz Walter

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Im Anschlus an eine Diskussion der Purpurogallinbildung durch oxydative Verschmelzung von 2 Moll. Pyrogallol wird die Hydrolyseempfindlichkeit 2-substituierter 2-Phenyl-indandione-(1.3) gegen Alkali studiert. Modellverbindungen mit Hydroxyl- und Aminogruppen in 2-Stellung hydrolysieren auserordentlich rasch. Dieses Verhalten stutzt die Annahme, das Purpurogallin uber ein Zwischenprodukt der Struktur III gebildet wird.

year	journal	country	edition	language
1961-11-01	Chemische Berichte

https://doi.org/10.1002/cber.19610941108

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