6533b81ffe1ef96bd1278446
RESEARCH PRODUCT
Synthesis and properties of polymers with unusual structure
Rolf C. Schulzsubject
chemistry.chemical_classificationchemistry.chemical_compoundCrystallinitychemistryBicyclic moleculeElectrophilePolymer chemistryPolyamideCyclohexeneCopolymerOrganic chemistryPolymerAlkylationdescription
This lecture summarize some recent results of our current research. The first part describes the homopolymerization and copolymerization of a monocyclic and two bicyclic unsaturated acetals. In this way polyacetals with 1,4-cis-butadiene units and cyclohexene units respectively are obtained. Secondly, the N-substitution of polyamides is described. By N-metalation and subsequent alkylation comb-like polyamides are available. Longer branches cause a side-chain crystallinity. The anionic “grafting-from” technique forms irregular branched polyamides. By termination reaction between living ends of poly(2-isopropenylnaphthalene) and suitable electrophiles new macromonomers are available. The last part describes their copolymerization with butyl methacrylate.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1985-05-01 | Die Makromolekulare Chemie |