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RESEARCH PRODUCT

A Superoxovanadium(V) Complex Linking the Peroxide and Dioxygen Chemistry of Vanadium.

Hans-jörg KrügerHarald Kelm

subject

ChemistryRadicalVanadiumchemistry.chemical_elementGeneral MedicineGeneral ChemistryReaction intermediateOxidative phosphorylationPhotochemistryPeroxideOxygenCatalysischemistry.chemical_compoundMolecular oxygen

description

A missing link: A superoxovanadium(V) complex is the first reaction intermediate in the oxidative conversion of a peroxovanadium(V) complex into a vanadyl(IV) complex and molecular oxygen. The superoxo species appears also to play an essential role in the formation of the peroxovanadium(V) complex from the vanadyl(IV) complex and molecular oxygen.

https://pubmed.ncbi.nlm.nih.gov/29711839